By Stuart A. Rice

This sequence presents the chemical physics box with a discussion board for severe, authoritative reviews of advances in each quarter of the self-discipline. This stand-alone precise subject matters quantity reviews contemporary advances in electron-transfer study with major, updated chapters through the world over well-known researchers.

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Extra info for Advances in Chemical Physics, Vol. 138

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Symmetry in Double Space A useful property of the double space is that it clarifies the treatment of symmetry [28]. In the single space, the symmetry of ÉG can appear confusing, because it depends on the position of the cut line. One way to avoid this confusion is to consider the symmetry of the total (electronic þ nuclear) wave function ÉÈ, which is of course independent of the position of the cut line [6, 7]. Another way is to map ÉG onto the double space. In Section II, we explained that ÉN and ÉG are respectively symmetric and ^ 2p in the double space.

Methods for solving the resulting equations are discussed in Section III. Section IV is devoted to a discussion of the Electric Nuclear Born–Oppenheimer (ENBO) approximation [41, 42]. This approximation provides a practical way of including polarization effects in coherent control calculations of molecular dynamics. In general, such effects are important as high electric fields often occur in the laser pulses used experimentally or predicted theoretically for such processes. The limits of validity of the ENBO approximation are also discussed in this section.

T. Sutcliffe, J. Chem. Phys. 77, 4061 (1982). 68. M. S. Child, Molecular Collision Theory, Academic Press, London, 1974. 42 stuart c. althorpe, juan carlos juanes-marcos, and eckart wrede 69. A. J. Dobbyn, P. McCabe, J. N. L. Connor, and J. F. Castillo, Phys. Chem. Chem. Phys. 1, 1115 (1999). 70. D. G. Truhlar and J. T. Muckerman in Atom–Molecule Collision Theory, R. B. ), Plenum, New York 1979. 71. F. J. Aoiz, V. J. Herrero, and V. Sa´ez Ra´banos, J. Chem. Phys. 94, 7991 (1991). 72. L. -C. Rayez, Chem.

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Advances in Chemical Physics, Vol. 138 by Stuart A. Rice
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