By C. L. Young, P. G. T. Fogg

This quantity provides a finished assortment and demanding evaluate of solubility facts released ahead of June 1983 for the compounds of the identify. quite a few suggestions have been utilized in the unique determinations; the advantages of those were thought of within the overview of the information. rising styles of solubility behaviour for similar structures are indicated. The editors think that the booklet will either draw awareness to parts the place solid facts are missing and stimulate additional experimental paintings.

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Additional resources for Ammonia, Amines, Phosphine, Arsine, Stibine, Silane, Germane and Stannane in Organic Solvents. Ammonia, Amines, Phosphine and Arsine in Organic Solvents

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The liquid was magnetically stirred and the final pressure of gas in contact ESTIMATED ERROR: with solvent was measured. REFERENCES: 1. 2. Timmermans, J. Physicfo-Chemical Constants of Pure Organic Cowpounds, Vol. II, Elsevier, Amsterdam, 1 9 6 5 . Braude, G. ; Leites, I. ; Dedova, I. V. Khim. Prom. 1 9 6 1 , 2 3 2 .

Baker Chemical Co. 99 percent. Used approximately 15 cm^ volume is as received. partly filled with solvent and closed with a half-hole septum. An amount of (2) l,l*Bicyclohexyl. Fluka. purum the gaseous solute is added to the grade. Impurities which give the container. The closed container is same retention time as the gas shaken for 30 minutes. Samples of are removed before the experi­ both the vapor and liquid phases are ment by adsorption or distilla­ taken in calibrated syringes. The tion. samples are injected into a gas Chromatograph.

M. two stage vacuum process described J. Phys. Chem. 1 9 5 7 , 61, by Clever et a l . ( 1 ) . 1078. 48 A m m o n i a Solubilities COMPONENTS: ORIGINAL MEASUREMENTS: 1. Ammonia; NH3; 2. Octanol; CeHigO; Gerrard, W. K. Chem. Ind. 1970, 925-926. K. Thesis, Univ. of London, 1970. T. Fogg. 56 Tlie variation of moles ^1 ^^"^^ /moles ^ „ ^ (ρ„„ = 1 atm) with temperature from 263 Κ to 293 Κ was given in graphical form. The variation of moles /moles _ „ . 2 K) with NH3 CeHiqO pressure from 0 to 1 atm was also given in the form of a graph.

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Ammonia, Amines, Phosphine, Arsine, Stibine, Silane, Germane by C. L. Young, P. G. T. Fogg
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