By James Morrison (Eds.)

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Colby, Β. N . , and McCaman, M. W. (1979). Biol. Mass Spectrosc. 6, 225. Cope, A. C , Funke, W. , and Jones, F. N. (1966). J. Am. Chem. Soc. 88, 4693. Eliel, E. L. (1962). "Stereochemistry of Carbon Compounds," p. 31. McGraw-Hill, New York. , and Lehner, Η. (1971). Tetrahedron 27, 2279. 58 Κ. Κ. A n d e r s e n , D. Μ. Gash, and J. D . , and Audisio, G. (1970). Tetrahedron 26, 1839. Gerlach, H. (1966). Helv. Chim. Acta 49, 2481. Goering, H. , and Doi, J. T. (1960). J. Am. Chem. Soc. 82, 5850. Goering, H.

J. Am. Chem. Soc. 92, 4906. Beckwith, J. , and Hager, L. P. (1961). J. Org. Chem. 26, 5206. Berson, J. , and Ben-Efraim, D. A. (1959). J. Am. Chem. Soc. 8 1 , 4083. Berson, J. Α . , and Suzuki, S. (1959). J. Am. Chem. Soc. 8 1 , 4088. Berson, J. , and Willner, D. (1964). J. Am. Chem. Soc. 86, 610. Campbell, I. M. (1974). Bioorg. Chem. 3 , 386. Colby, Β. N . , and McCaman, M. W. (1979). Biol. Mass Spectrosc. 6, 225. Cope, A. C , Funke, W. , and Jones, F. N. (1966). J. Am. Chem. Soc. 88, 4693. Eliel, E.

If χ represents the extent of the reaction, then p Fig. 2. N Variation of the enantiomeric purity P A as a function of time. 3. C o m p e t i t i v e Reaction M e t h o d s 33 x (%) Fig. 3 . Relation b e t w e e n enantiomeric purity P and extent of the reaction χ as a function of the ratio Κ = k /k . 02. A p Χ = ([Α N ] + + 0 [Α_] ) - ([Α 0 [Α ] + 0 + + [Α_] ] + [Α_]) _ = 0 [Α + ] + [Α + ] [Α_] + [Α_] 0 0 ' By the use of Eqs. (1) and (3), the following conclusion can be reached: a —k t e _L p.

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Asymmetric Synthesis by James Morrison (Eds.)
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