By Tobin J. Marks

content material: value of metal-ligand bond energies in organometallic chemistry: an outline / Tobin J. Marks --
Periodic tendencies in transition steel bonds to hydrogen, carbon, and nitrogen / Peter B. Armentrout --
Organometallic response energetics from product kinetic power unlock distributions / Petra A.M. van Koppen, Michael T. Bowers, J.L. Beauchamp, and David V. Dearden --
tools for identifying metal-ligand and metal-metal bond energies utilizing fourier rework mass spectrometry / Ben S. Freiser --
Gas-phase thermochemistry of organometallic and coordination complicated ions / David E. Richardson, Charles S. Christ, Jr., Paul Sharpe, Matthew F. Ryan, and John R. Eyler --
Ionization energy-bond power relationships in organometallic chemistry / Dennis L. Lichtenberger and Ann S. Copenhaver --
Thermodynamics and kinetics of transition metal-alkyl homolytic bond dissociation procedures / Jack Halpern --
Cage pair intermediates and activation parameters / T. Koenig, T.W. Scott, and James A. Franz --
Thermodynamic and kinetic stories of binding nitrogen and hydrogen to complexes of chromium, molybdenum, and tungsten / Alberto A. Gonzalez, Kai Zhang, Shakti L. Mukerjee, Carl D. Hoff, G. Rattan okay. Khalsa, and Gregory J. Kubas --
Thermodynamic experiences of the hydrogenation and reductive coupling of carbon monoxide by means of rhodium(II) porphyrins / Bradford B. Wayland, Virginia L. Coffin, Alan E. Sherry, and William R. Brennen --
steel and ancillary coordination results on organolanthanide-ligand bond enthalpies : implications for bonding and response styles / Steven P. Nolan, David Stern, David Hedden, and Tobin J. Marks --
Novel extensions of the electrostatic covalent process and calorimetric measurements to organometallic structures / Russell S. Drago --
Metal-ligand bond dissociation energies in CpMn(CO)₂L and Cr(CO)₅(olefin) complexes / Jane okay. Klassen, Matthias Selke, Amy A. Sorensen, and Gilbert ok. Yang --
Metal-carbon and metal-hydrogen bond dissociation enthalpies from classical and nonclassical calorimetric reviews / A.R. Dias, H.P. Diogo, D. Griller, M.E. Minas da Piedade, and J.A. Martinho Simões --
Adsorbate-induced restructuring of surfaces : floor thermodynamic puzzle / G.A. Somorjai --
Acid websites on chemically converted molybdenum surfaces / Peter C. Stair --
Absolute electronegativity, hardness, and bond energies / Ralph G. Pearson --
Gas-phase chemistry of first-row transition steel ions with nitrogen-containing compounds : theoretical and experimental investigations / A. Mavridis, ok. Kunze, J.F. Harrison, and J. Allison --
Periodic traits within the bond energies of transition steel complexes : density useful concept / Tom Ziegler and Vincenzo Tschinke.

Show description

Read or Download Bonding Energetics in Organometallic Compounds PDF

Similar physical chemistry books

The Surface Chemistry of Natural Particles

This booklet recounts the improvement of test and conception in typical particle floor chemistry over the last twenty years. It deals a largely dependent dialogue of molecular spectroscopy, kinetics, and equilibria as they practice to normal particle floor reactions in aqueous media, with emphasis on insights won during the last few years.

Rheology for Chemists: An Introduction

''. .. well-suited for self-study via learn employees and technologists, who, faced with technical difficulties during this quarter, would prefer a simple creation to the topic of rheology. '' Chemical Educator, ''. .. filled with worthwhile insights and updated details. '' Chemistry global.

Materials Issues in a Hydrogen Economy: Proceedings of the International Symposium Richmond, Virginia, USA 12-15 November 2007

This lawsuits quantity of the overseas Symposium on fabrics concerns in a Hydrogen economic climate addresses primary fabrics technological know-how concerns and demanding situations about the construction, garage, and use of hydrogen. the quantity additionally offers with protection and schooling concerns. The members - researchers in physics, chemistry, fabrics technology, and engineering - proportion their rules and effects to delineate notable fabrics difficulties in a hydrogen economic climate and to steer the long run learn.

Extra resources for Bonding Energetics in Organometallic Compounds

Example text

Buckner, S. ; F r e i s e r , B. S. J . Am. Chem. Soc. 1987, 109, 4715. S c h u l t z , R. ; Armentrout, P. B. work i n progress. "Burnier, R. ; Byrd, G. ; F r e i s e r , B. S. J . Am. Chem. Soc. 1981, 103. 4360. Buckner, S. ; Gord, J . ; F r e i s e r , B. S. J . Am. Chem. Soc. 1988, 110. 6606. H e t t i c h , R. ; F r e i s e r , B. S. J . Am. Chem. Soc. 1986, 108, 2537. E l k i n d , J . ; Armentrout, P. B. J . Phvs. Chem. 1986, 9Q, 6576. ; Fisher, E. ; Armentrout, P. B. J . Am. Chem. Soc. 1989, 111, 4251.

Metal c l u s t e r s . We have recently published the f i r s t measurements of the binding energies f o r t r a n s i t i o n metal c l u s t e r s larger than the dimers (39,40, Hales, D. ; Armentrout, P. B. J . Cluster Science submitted f o r p u b l i c a t i o n ) . This work i s being extended to other metals and to the chemistry of such species. We have also recently developed a flowing afterglow source f o r our guided ion beam apparatus. This source i s designed to produce ions that are therraalized i n a l l degrees of freedom.

The two lone p a i r s can be seen to each make a s i m i l a r 28 kcal/mol c o n t r i b u t i o n each i n the V0H case, Figure 3. Z i e g l e r et a l . have calculated a s i m i l a r r e s u l t f o r the series of saturated species, C i T i - L , f i n d i n g the Ti-OH bond to be 21 kcal/mol stronger than the Ti-NH bond which i s 23 kcal/mol stronger than the Ti-CH bond (17). For metal ions on the r i g h t side of the p e r i o d i c t a b l e , the picture i s less clear-cut. One would a n t i c i p a t e that the lone p a i r e f f e c t w i l l be reduced since there are no longer any empty o r b i t a l s on the metal to accept the lone p a i r donation.

Download PDF sample

Bonding Energetics in Organometallic Compounds by Tobin J. Marks
Rated 4.42 of 5 – based on 42 votes