By Priv.-Doz. Dr. Günter Häfelinger (auth.)

Show description

Read Online or Download π Complexes of Transition Metals PDF

Best organic books

Dictionary of Food Compounds with CD-ROM: Additives, Flavors, and Ingredients

The Dictionary of foodstuff Compounds with CD-ROM: ingredients, Flavors, and materials presents entire info on 30,000 compounds present in foodstuff, including:NATURAL meals CONSTITUENTSLipidsProteinsCarbohydratesFatty acidsFlavonoidsAlkaloidsFOOD ADDITIVESColorantsPreservativesAntioxidantsFlavorsFOOD CONTAMINANTSMycotoxinsNUTRACEUTICALSProbioticsDietary SupplementsVitamins

The Molecular and Supramolecular Chemistry of Carbohydrates: Chemical Introduction to the Glycosciences

Present study in carbohydrates is starting to diversity throughout conventional divisions in chemistry and biology, giving upward push to a brand new interdisciplinary box, glycoscience. The growing to be curiosity in glycoscience stems from the invention that oligosaccharides play an incredible position in popularity occasions and from the transforming into call for for chiral synthesis, on account that sugars gives you an amazingly affordable resource of chiralitiy.

Keynotes in organic chemistry 2e

This concise and obtainable publication offers natural chemistry notes for college kids learning chemistry and similar classes at undergraduate point, protecting center natural chemistry in a structure perfect for studying and swift revision. the cloth is organised in order that primary techniques are brought early, then equipped directly to supply an summary of the necessities of practical workforce chemistry and reactivity, major the coed to a pretty good figuring out of the fundamentals of natural chemistry.

Extra resources for π Complexes of Transition Metals

Example text

R'X R ' - C H 2 - C = C H 2 + 2NIX2 I R The synthesis o f o~-santalene from ot,a-dimethylallyl bromide via 7r-allyl nickel complex is an elegant application. 51 J. Tsuji On the other hand, Tsuji, Morikawa, and Takahashi found that zr-allyl palladium complexes react with nucleophiles, such as amines and enamines, and active methylene compounds, such as malonates, with reduction of bivalent palladium to the zero-valent metal 39,4o). This is due to the stability of the reduced species. Pd + CH2(CO2R)2 ' CH2=CH-CH2-CH(CO2R)2 In the dimerization reaction ofbutadiene catalyzed by palladium complexes, nucleophiles (YH), such as amines, alcohols, phenols, carboxylic acids 41-4s), and active methylene compounds 46) are introduced.

The Dithiocarbomates and Related Compounds. Amsterdam: Elsevier Monographs 1962. : Acta Cryst. 19, 619 (1965). : Acta Cryst. 19, 886 (1965). Acta Cryst. 19, 898 (1965). : J. Am. Chem. Soc. 75, 2163 (1953). - lron(II)Diimine and Related Complexes. In: Structure and Bonding, Vol. 9, p. 139. Berlin-Heidelberg-New York: Springer 1971. Figgins, P. , Busch, D. : J. Am. Chem. Soc. 82, 820 (1960). : Angew. Chem. 73, 533 (1961). : Angew. Chem. 76, 76 (1964). Schrauzer, G. : Advan. Organometal. Chem. 2, 17 (1964).

II. a-Bond F o r m a t i o n . . . . . . . . . . 1. Oxidative A d d i t i o n Reactions . . . . . . . 2. Reactivity of a-Bonds . . . . . . . . 3. Oxidative Metal-Metal Bond Cleavage . . . . . 4. Reactions of Transition Metal C o m p o u n d s with Organometallic Compounds . . . . . . . . . . 5. F o r m a t i o n o f Metal Carbonylate Anions from Metal Carbonyls and Their Reactions . . . . . . . . . III. Insertion Reactions . . .

Download PDF sample

π Complexes of Transition Metals by Priv.-Doz. Dr. Günter Häfelinger (auth.)
Rated 4.45 of 5 – based on 31 votes