By Alan R. Katritzky, Otto Meth-Cohn, and Charles W. Rees (Editors-in-Chief)

This quantity covers the formation of carbon-carbon single-, double- and triple bonds by way of substitution and addition reactions in addition to by means of a variety of rearrangements. The formation of carbon-carbon a number of bonds by way of removal and condensation methods is absolutely documented. moreover the synthesis of carbon-hydrogen bonds mostly via substitution and addition reactions is featured as is the training of a wide selection of carbon-centred anions, cations and radicals.

Show description

Read Online or Download Comprehensive Organic Functional Group Transformations,Volume 1 (Synthesis: Carbon with No Attached Heteroatoms) PDF

Similar organic books

Dictionary of Food Compounds with CD-ROM: Additives, Flavors, and Ingredients

The Dictionary of meals Compounds with CD-ROM: ingredients, Flavors, and components offers complete info on 30,000 compounds present in nutrition, including:NATURAL nutrition CONSTITUENTSLipidsProteinsCarbohydratesFatty acidsFlavonoidsAlkaloidsFOOD ADDITIVESColorantsPreservativesAntioxidantsFlavorsFOOD CONTAMINANTSMycotoxinsNUTRACEUTICALSProbioticsDietary SupplementsVitamins

The Molecular and Supramolecular Chemistry of Carbohydrates: Chemical Introduction to the Glycosciences

Present learn in carbohydrates is starting to variety throughout conventional divisions in chemistry and biology, giving upward push to a brand new interdisciplinary box, glycoscience. The turning out to be curiosity in glycoscience stems from the invention that oligosaccharides play a major position in popularity occasions and from the growing to be call for for chiral synthesis, considering the fact that sugars grants an amazingly affordable resource of chiralitiy.

Keynotes in organic chemistry 2e

This concise and available e-book presents natural chemistry notes for college kids learning chemistry and comparable classes at undergraduate point, masking center natural chemistry in a structure excellent for studying and speedy revision. the cloth is organised in order that basic ideas are brought early, then outfitted directly to offer an summary of the necessities of useful crew chemistry and reactivity, best the coed to a superb realizing of the fundamentals of natural chemistry.

Additional info for Comprehensive Organic Functional Group Transformations,Volume 1 (Synthesis: Carbon with No Attached Heteroatoms)

Sample text

O} experiment would be prohibitive\ and second the catalyst requires a high percentage of platinum\ thus making the method costly[ Another ~ow method was used to reduce cyano! Ethyladamatane 83 Benzonitrile Methylcyclohexane 64 ÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐ * 30% Ni–Al2O3 CN (35) 180 °C, H2 99% 0[91[0[2[2 Reduction using hydride reagents The use of hydrides for the reduction of nitriles to the methyl analogue seems to have been scarcely investigated to any degree[ Sodium borohydride in acetonitrile was used to reduce p!

ClC5H3CH1 51 ÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐ * Primary arylamines make up the third and _nal group[ The method described above for alkyl! di! phenyl ! 4\5 ! dihydrobenzoðhŁquinolin! 2! 2! 2! Ethylpentane 77 Aniline Cyclohexane 88 Diphenylamine Cyclohexane 88 ÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐÐ * Pt, H2 + N Pt, H2 + N H Scheme 7 In all\ this is a good method for defunctionalizing simple amines to their corresponding hydro! butyltin hydride was used to reduce a series of similar compounds as shown in Scheme 7 ð77SC0196Ł[ This appears to be the only examination of this reagent as an amine reductant[ Tem!

Ophilic hydride which may be used for the reductive displacement of disulfonimides[ The incor! yielding method of producing disulfonimides from hindered amines has been found[ It appears that sulfonamides resist addition of a second sulfonyl moiety in even moderately hindered environments[ Research has suggested that the steric requirement of the disulfonimide surpasses that of the trimethylammonium ion ð55LA"580#04\ 64JA5762Ł[ The range of compounds investigated in this type of reduction spans several substituted aniline and straight chain primary amine deriva!

Download PDF sample

Comprehensive Organic Functional Group by Alan R. Katritzky, Otto Meth-Cohn, and Charles W. Rees
Rated 5.00 of 5 – based on 26 votes