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Microchip Technol. 8, 45252. 24. , and De Smet, M. (2004). Beckman P/ACE-Setter 8, 124. 25. , Bruin, G. J. , and Bruno, A. E. (1994). Anal. Chem. 66, 1. 26. , Cassidy, R. , and Baranski, A. S. (1993). J. Chromatogr. 640, 433. 27. Ewing, A. , Mesaros, J. , and Gavin, P. F. (1994). Anal. Chem. 66, 527A. 28. , Lucky, J. , Gordon, M. , and Zare, R. N. (1989). Anal. Chem. 61, 766. 29. Jones, W. , and Reineck, J. (1994). Paper presented at the International Ion Chromatography Symposium 1994, Turin, Italy paper No.

If a solute is highly hydrophobic and therefore has a very strong affinity for the inner part of the micelles, then it will migrate with the mobility of the micelles. In other words, the solutes are partitioned between the micellar and aqueous phase. For this reason the technique is called micellar electrokinetic capillary chromatography, abbreviated as MECC or MEKC. The most applied surfactant in MEKC is sodium dodecyl sulfate (SDS). Figure 12 shows a schematic representation of the mechanisms in MEKC.

1, 144. 58. Monnig, C. , and Kennedy, R. T. (1994). Anal. Chem. 66, 280R. 59. Gurley, L. , Buchanan, J. , London, J. , Stavert, D. , and Lehnert, B. E. (2001). J. Chromatogr. A 559, 411. 60. Rill, R. , Van Winkle, D. , and Locke, B. R. (1998). J. Chromatogr. A 817, 2872295. 61. , and Massart, D. L. (1995). J. Chromatogr. A 706, 479. 62. , and Massart, D. L. (1996). Trends Anal. Chem. 15, 91. 63. , and Musch, G. (1998). Biomed. Chromatogr. 12, 1282130. 64. Khaledi, M. , Smith, S. , and Strasters, J.

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Computational Chemistry Using the PC by D. Rodgers
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