By Wilson E.B.

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Radatua, Can. J . , 48,2146 (1970). A. Nishimura, M. Ohts, and H. Kato, Bull. Soc. Japan, 48,1630 (1970). Bozimo, and P. Wolf, Tetrahedron Letteru, 1970,2396. 168 168 R. Maurin and M. Bertrand, TetraMrm Letter4 1970,1307. l a 8 S. Hariya and S. Terasewa, Nip* Kagak Zmehi, 90,766 (1969); Chem. , 71,123143 ( 1969). 170 M. Julia and C. Descoins, Bull. Soe. Chim. France, 1970, 1806,1816,1822. G. Cfassman and A. F. J. Am. Chem. 92,2662 , (1970). '~'This was interpreted as resulting from the relative orientation of the u-bond of the cyclopropyl group and the n-orbital of the double bond towards the developing carbonium ion centre.

101,3711 (1970). 188 W. E. Parham and K. 9. Yong,J . Org. , 85,683 (1970). 189 D. E. Applequist, M. R. Binher, J . Am. Chm. , 92,4614 (1970). ma P. G. Gaaaman, D. Dygoe, and J. Trent, J . Am. Chem. 2084 (1970); 888 047. , 1969,1008; see also S. P. MoManm, and C. U. Pittman, J . , S6, 186 187 1187 (1970). 191 J. Meinwald and T. N. Wheeler,J . Am. Chem. , 92, 1009 (1970). 44 Organic Reaction Mechniisms 1970 products. Similar producte were obtained from the hydrolysis of the corresponding 16/3-&ezotatee and solvolysis of the 16/3-toluene-p-sulphonates.

Trav. ,89,1070 (1070). 145 H. Hogevean and C. J. Gaesbeak, Rec. Trav. , 88,395 (1970). 146 D. Brouwer and J. A. van Doom, Rec. Tmu. ,89,663 (1970). 14* 149 R. 14' Primary homopropargyl sulphonates, as (Mi),yield predominantly 2-alkylThe cyclobutanones on solvolysis in formic acid and trifluoroacetic influence of substitution at the acetylenic carbon has been investigated. 1 1 0 R 0 Smaller amounte of cyclobutanones are formed from the reaction of secondary homopropargyl sulphonates. 14QThe solvolyses of (90) and (91) are slow because the cyclopropyland methylene groups are restricted into a conformation in which conjugation with the carbonium ion centre is minimal.

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Coulombs Law and the Hydrogen Spectrum by Wilson E.B.
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