By Vadim A. Soloshonok, Koichi Mikami, Takashi Yamazaki, John T. Welch, John Honek

content material: Trifluoromethylatlon of steel enolates and theoretical instruction / Koichi Mikami and Yoshimitsu Itoh --
Syntheses of organofluorine derivatives by way of a brand new radical approach / Samir Z. Zard --
a topic of synthesis method: to make or quite to remodel organofluorine compounds / Manfred Schlosser, Qian Wang and Fabrice Cottet --
Nitrogen-containing organofluorine compounds via metathesis reactions / Santos Fustero ... [et al.] --
hugely diastereoselective anodic fluorination / Toshio Fuchigami and Toshiki Tajima --
A stereospecific access to functionalized cis-1,2-difluoroalkenes / Anilkumar Raghavanpillai and Donald J. Burton --
Stereoselective synthesis of polyfluorinated exo-tricyclononenes and norbonenes / Viacheslav A. Petrov --
Catalytic in-situ new release of trifluoroacetaldehyde from its hemiacetal and successive direct aldol response with ketones / Kazumasa Funabiki and Masaki Matsui --
Cationic cyclizations of fluoro alkenes: fluorine as a controller and an activator / Junji Ichikawa --
A hydro-fluoro hybrid compound, hermaphrodite, is fluorophilic or fluorophobic?: a brand new notion for the fluorine-based crystal engineering / T. Ono ... [et al.] --
Fluorous nanoflow microreactor: nanoflow microreactor with fluorous lanthanide catalysts for elevate in reactivity and selectivity / Koichi Mikami and Takayuki Tonoi --
Fluorous chemistry for synthesis and purification of biomolecules: peptides, oligasaccharides, glycopeptides, and oligonucleotides / Wei Zhang --
useful compounds in accordance with hypervalent sulfur fluorides / Peer Kirsch and Gerd-Volker Röschenthaler --
Synthesis of macrolactam marine traditional items utilizing fluorous preserving teams / Yutaka Nakamura and Seiji Takeuchi --
Carbohydrate microarrays and fluorous-phase synthesis: interfacing fluorous-phase faucet with the direct formation of glycoarrays / Nicola L. Pohl --
Fluorous carboxylates as priceless steel ligands for catalysts-products restoration approaches and sensing / Mounir El Bakkari and Jean-Marc Vincent --
Organofluorine chemistry on the biomedical interface: a case learn on fluoro-taxoid anticancer brokers / Iwao Ojima, Larissa V. Kuznetsova and Liang sunlight --
Synthesis of gem-difluoromethylated sugar nucleosides / Feng-Ling Qing and Xiao-Long Qiu --
Polyfluoropyridyl glycosyl donors / Christopher A. Hargreaves, Graham Sandford and Benjamin G. Davis --
New 10-trifluoromethyl monomers, dimers, and chimeras of artemisinin from a key allyl bromide precursor / Danièle Bonnet-Delpon ... [et al.] --
Synthesis of novel gem-difluorinatedcyclopropane hybrids: functions for fabric and medicinal sciences / Toshiyuki Itoh --
The synthesis of an antiviral fluorinated purine nucleoside : 3'-(alpha)-fluoro-2', 3'-dideoxyguanosine / Kunisuke Izawa ... [et al.] --
Solvent-peptide interactions in fluoroalcohol-water combos / C. Chatterjee, G. Hovagimyan and J.T. Gerig --
Fluorinated methionines as probes in organic chemistry / John F. Honek --
Synthesis and conformational research of fluorine-containing oligopeptides / Takashi Yamazaki, Takamasa Kitamoto and Shunsuke Marubayashi --
Fluorinated inhibitors of matrix metalloproteinases / Fiorenza Viani ... [et al.] --
utilizing fluorinated amino acids for constitution research of membrane-active peptides by way of solid-state (superscript 19)F-NMR / Parvesh Wadhwani ... [et al.] --
uneven synthesis of (beta)-trifluoromethylated (beta)-amiao carbonyl compounds in line with the 1,2-addition to trifluoroacetaldehyde SAMP- or RAMP-hydrazones / Kazumasa Funabiki ... [et al.] --
a singular approach for the synthesis of trifluoroalanine oligopeptides / Kenji Uneyama ... [et al.] --
Hyperstable collagen in response to 4-fluoroproline residues / Ronald T. Raines --
Fluorinated amino acids and reagents in protein layout and biomolecule separation / He Meng, Venkateshwarlu Kalsani and Krishna Kumar.

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Extra info for Current Fluoroorganic Chemistry. New Synthetic Directions, Technologies, Materials, and Biological Applications

Sample text

Synthesis of trifluoromethyl ketones. A simple trifluoromethyl group can be introduced via the corresponding xanthate. Such xanthates, however, and not surprisingly, cannot be made by a simple nucleophilic substitution on a trifluoromethyl halide, as in the case of the previous derivatives. A n indirect route via the decarbonylation of the 5trifluoroacyl xanthate 17 was devised to overcome this problem (8). A "heavier" xanthate was employed to aid in handling the intermediates and to avoid having to manipulate a potentially volatile reagent.

J. Fluorine Chem. 1997, 5 4 , 2 0 7 - 2 0 7 . (a) Lal, S. ; J. Org. Chem. 1993, 58, 2791 - 2796; (b) Matthews, D . ; Miller, S. ; Jarvi, E . ; Sabol, J. ; McCarthy, J. ; Tetrahedron Lett. 1993, 34, 3057 - 3060; (c) Banks, R. ; Pritchard, R. , Sect. C 1993, 49, 492 - 495 [Chem. Abstr. 1993, 118, 223259] (d) Banks, R. ; Lawrence, N. ; Popplewell, A. ; J. Chem. , Chem. Commun. 1994, 343 - 344. ; Chem. Ber. 1997, 102, 77 - 82. ; unpublished results (1998). Suga, H . ; Guggisberg, Y . ; Schlosser, M .

Quiclet-Sire, B . ; Zard, S. Z. Chem. Commun. 1996, 25112512. 8. ; Pevere, V . ; Quiclet-Sire, B . ; Zard, S. Z . Org. Lett. 2001, 3, 1069-1071. 9. ; Zard, S. Z. J. Am. Chem. Soc. 1996, 118, 9190-9191. 10. Liard, A . ; Quiclet-Sire, B . ; Zard, S. Z. Tetrahedron Lett. 1996, 37, 58775880. 11. ; Zard, S. Z. Chem. Commun. 2002, 2312-2313. 12. ; Pérez-Martin, I . ; Quiclet-Sire, B . ; Zard, S. Z. Org. Biomol. Chem. 2004, 2, 3018-3025. 13. ; Zard, S. Z. Tetrahedron Lett. 2005, 46, 7503-7506. 14. ; Zard, S.

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Current Fluoroorganic Chemistry. New Synthetic Directions, by Vadim A. Soloshonok, Koichi Mikami, Takashi Yamazaki, John
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